000 01907nab a2200313 c 4500
001 vtls000528377
003 RU-ToGU
005 20211202175334.0
007 cr |
008 181202|2015 ne s a eng dd
024 7 _a10.1016/j.molcata.2014.09.032
_2doi
035 _ato000528377
040 _aRU-ToGU
_brus
_cRU-ToGU
100 1 _aSalaev, Mikhail A.
_9563314
245 1 0 _aEthylene glycol oxidation over Ag-containing catalysts: A theoretical study
_cM. Salaev, O. K. Poleshchuk, O. V. Vodyankina
520 3 _aA theoretical interpretation of the mechanism of ethylene glycol oxidation to glyoxal over Ag-containing catalysts is considered. A model system, reflecting the interaction of Ag cluster with process adsorbates and/or intermediates, is proposed. Both partial oxidation of ethylene glycol to glyoxal and CO2 formation routes are reconstructed, and the corresponding reaction profiles are represented. The roles played by the most important reaction intermediates participating in the process under consideration are discussed.
653 _aэтиленгликоль
653 _aокисление
653 _aсеребро
655 4 _aстатьи в журналах
_9745982
700 1 _aPoleshchuk, Oleg Kh.
_9100314
700 1 _aVodyankina, Olga V.
_936805
710 2 _aТомский государственный университет
_bХимический факультет
_bКафедра физической и коллоидной химии
_983087
773 0 _tJournal of molecular catalysis A : chemical
_d2015
_gVol. 396. P. 61-67
_x1381-1169
852 4 _aRU-ToGU
856 7 _uhttp://vital.lib.tsu.ru/vital/access/manager/Repository/vtls:000528377
908 _aстатья
999 _c523255