000 02448nab a2200337 c 4500
001 vtls000795702
003 RU-ToGU
005 20220628162647.0
007 cr |
008 210319|2020 ne s a eng d
024 7 _a10.1016/j.combustflame.2019.12.021
_2doi
035 _ato000795702
040 _aRU-ToGU
_brus
_cRU-ToGU
100 1 _aMursalat, Mehnaz
_9510837
245 1 0 _aEffect of premilling Al and CuO in acetonitrile on properties of Al·CuO thermites prepared by arrested reactive milling
_cM. Mursalat, M. Schoenitz, E. L. Dreizin
336 _aТекст
337 _aэлектронный
504 _aБиблиогр.: 21 назв.
520 3 _aThermite powders with molar composition 8Al·3CuO were prepared in two stages by Arrested Reactive Milling (ARM). In the first stage, the starting materials Al and CuO were milled separately in acetonitrile. Composite powders were then prepared in the second milling stage with hexane as process control agent and in the four possible combinations of one, both, or neither starting material being premilled in acetonitrile. Composites were characterized for morphology, size distribution, surface area, and reactive properties at low heating rates (thermal analysis) and high heating rates (ignition). Whether or not CuO was premilled, dense composites formed without premilling of Al. If Al was premilled in acetonitrile, however, loose agglomerates of refined Al and CuO particles formed in the second milling stage. Premilling changed the low-temperature reactions leading to ignition in the 8Al·3CuO thermites. These changes are attributed to increased porosity of the formed composites if aluminum is premilled with acetonitrile. It is shown that greater refinement and lower ignition temperatures are achievable using two-stage milling.
653 _aреактивные материалы
653 _aмеханическое измельчение
653 _aацетонитрил
655 4 _aстатьи в журналах
_9745982
700 1 _aSchoenitz, Mirko
_9363924
700 1 _aDreizin, Edward L.
_9363925
773 0 _tCombustion and flame
_d2020
_gVol. 214. P. 57-64
_x0010-2180
_w0210-36960
852 4 _aRU-ToGU
856 4 _uhttp://vital.lib.tsu.ru/vital/access/manager/Repository/vtls:000795702
908 _aстатья
999 _c480375