000 02318nab a2200325 c 4500
001 vtls000624958
003 RU-ToGU
005 20211202175131.0
007 cr |
008 180416|2016 fr s a eng d
024 7 _a10.1051/matecconf/20164104001
_2doi
035 _ato000624958
040 _aRU-ToGU
_brus
_cRU-ToGU
245 1 0 _aDevelopment of layered anode structures supported over Apatite-type Solid Electrolytes
_cP. Pandis, T. S. Kharlamova, V. A. Sadykov, V. N. Stathopoulos
504 _aБиблиогр.: 12 назв.
520 3 _aApatite-type lanthanum silicates (ATLS) materials have attracted interest in recent literature as solid electrolytes for SOFCs. The fabrication of an ATLS based fuel cell with the state-of-art electrodes (NiO/YSZ as anode and LSCF or LSM as cathode) can show degradation after long operation hours due to Si diffusion mainly towards the anode. In this work, we report a “layer-by-layer anodic electrodes” fabrication by means of spin coating and physical spraying. The overall aim of this work is the successful fabrication of such a layered structure including suitable blocking layers towards the inhibition of Si interdiffusion from the apatite electrolyte to the anode. The results showed that the deposition of 3 layers of LFSO/GDC (3μm), NiO/GDC (4μm) and the final NiO/YSZ anode layer provided a stable half-cell, with no solid state reaction occurring among the electrodes and no Si diffusion observed towards the anode after thermal treatment at 800°C for 120h.
653 _aтвердые электролиты
653 _aсиликаты лантана со структурой апатита
653 _aанодные электроды
655 4 _aстатьи в журналах
_9745982
700 1 _aPandis, P.
_9482562
700 1 _aSadykov, Vladislav A.
_999161
700 1 _aStathopoulos, V. N.
_9482563
700 1 _aKharlamova, Tamara S.
_999160
773 0 _tMATEC Web of conferences
_d2016
_gVol. 41. P. 04001 (1-4)
_x2261-236X
852 4 _aRU-ToGU
856 7 _uhttp://vital.lib.tsu.ru/vital/access/manager/Repository/vtls:000624958
908 _aстатья
999 _c434718