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008 170213s2015 ne | s |||| 0|eng d
020 _a9789048128792
_9978-90-481-2879-2
024 7 _a10.1007/978-90-481-2879-2
_2doi
035 _ato000562397
040 _aSpringer
_cSpringer
_dRU-ToGU
050 4 _aQD450-882
072 7 _aPNR
_2bicssc
072 7 _aSCI013050
_2bisacsh
082 0 4 _a541
_223
100 1 _aBonnelle, Christiane.
_eauthor.
_9471407
245 1 0 _aRare-Earths and Actinides in High Energy Spectroscopy
_helectronic resource
_cby Christiane Bonnelle, Nissan Spector.
250 _a1st ed. 2015.
260 _aDordrecht :
_bSpringer Netherlands :
_bImprint: Springer,
_c2015.
300 _aXVII, 380 p. 120 illus., 107 illus. in color.
_bonline resource.
336 _atext
_btxt
_2rdacontent
337 _acomputer
_bc
_2rdamedia
338 _aonline resource
_bcr
_2rdacarrier
490 1 _aProgress in Theoretical Chemistry and Physics,
_x1567-7354
505 0 _aIntroduction -- Electron distributions and crystalline structures -- Electron distributions and physico-chemical properties -- High energy spectroscopy and resonance effects -- Rare earths Spectroscopy -- Actinide  spectroscopy.
520 _aThis unique monograph covers recent theoretical and experimental results on the complex character of f electrons in materials containing lanthanides (rare earths) or actinides, such as alpha-cerium and delta-plutonium. It answers the urgent need for a general presentation of the body of experimental and theoretical results presently available in this challenging domain. Some of the fast developing applications of lanthanide and actinide materials are mentioned. Materials containing atoms with an open f shell have electronic and crystalline properties that are controlled by the localized or delocalized character of the f electrons. This book gives a theoretical discussion of the various spectroscopic methods that shed light on the character of the f electrons and on the connection between their localization and the properties of these materials. Part 1 covers the characteristics of the f electrons in atoms and solids and includes a discussion of the properties of lanthanides and actinides in connection with the f electrons. Part 2 describes the various spectroscopic methods that are used to establish the electronic distributions and energies of the states. Examples involve the determination of f electron distributions by high energy spectroscopy methods with separate treatment of the valence and core electrons. Part 3 concentrates on the theoretical treatment of electronic transitions involving f electrons and simulations of the lanthanide spectra, including comparison with the available experimental data. Part 4 discusses the localized or delocalized character of the f electrons in actinides and their compounds, including comparison (analogies & differences) between the 4f and 5f electron materials. This monograph should be of great value for researchers, academics and engineers working in the fields of high energy spectroscopy, electronic and nuclear science and technology, as well as materials involving rare earths and radio-elements.
650 0 _achemistry.
_9161768
650 0 _aPhysical Chemistry.
_9566251
650 0 _aChemistry, Physical and theoretical.
_9382528
650 0 _aMaterials Science.
_9143944
650 1 4 _aChemistry.
_9161768
650 2 4 _aPhysical Chemistry.
_9566251
650 2 4 _aTheoretical and Computational Chemistry.
_9307180
650 2 4 _aMaterials Science, general.
_9309901
700 1 _aSpector, Nissan.
_eauthor.
_9471409
710 2 _aSpringerLink (Online service)
_9143950
773 0 _tSpringer eBooks
830 0 _aProgress in Theoretical Chemistry and Physics,
_9309383
856 4 0 _uhttp://dx.doi.org/10.1007/978-90-481-2879-2
912 _aZDB-2-CMS
999 _c417664