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003 | RU-ToGU | ||
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007 | cr nn 008mamaa | ||
008 | 160915s2014 gw | s |||| 0|eng d | ||
020 |
_a9783319026602 _9978-3-319-02660-2 |
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024 | 7 |
_a10.1007/978-3-319-02660-2 _2doi |
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035 | _ato000542329 | ||
040 |
_aSpringer _cSpringer _dRU-ToGU |
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050 | 4 | _aQC176.8.S8 | |
050 | 4 | _aQC611.6.S9 | |
050 | 4 | _aQC176.84.S93 | |
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_aPHFC _2bicssc |
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072 | 7 |
_aSCI077000 _2bisacsh |
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082 | 0 | 4 |
_a530.417 _223 |
100 | 1 |
_aKrull, Cornelius. _eauthor. _9448775 |
|
245 | 1 | 0 |
_aElectronic Structure of Metal Phthalocyanines on Ag(100) _helectronic resource _cby Cornelius Krull. |
260 |
_aCham : _bSpringer International Publishing : _bImprint: Springer, _c2014. |
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300 |
_aXVII, 146 p. 81 illus., 54 illus. in color. _bonline resource. |
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336 |
_atext _btxt _2rdacontent |
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337 |
_acomputer _bc _2rdamedia |
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338 |
_aonline resource _bcr _2rdacarrier |
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490 | 1 |
_aSpringer Theses, Recognizing Outstanding Ph.D. Research, _x2190-5053 |
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505 | 0 | _aAbstract -- Introduction -- Molecular electronics -- Experimental techniques -- Introduction to the Kondo effect -- Adsorption of Metal Phthalocyanines on Ag(100) -- Electronic and magnetic properties of MePc on Ag(100) -- Doping of MePc: Alkali and Fe atoms -- Conclusions and Outlook -- Appendix: CuPc on Au(111). | |
520 | _aThe application of molecules in technological devices hinges on the proper understanding of their behavior on metallic electrodes or substrates. The intrinsic molecular electronic and magnetic properties are modified at a metallic interface, and greatly depend on the atomic configuration of the molecule-metal bond. This poses certain problems, such as the lack of reproducibility in the transport properties of molecular junctions, but also offers the possibility to induce new charge and spin configurations that are only present at the interface. The results presented in this thesis address this issue, providing a comprehensive overview of the influence of molecule-metal and molecule-molecule interactions on the electronic and magnetic properties of molecules adsorbed on metallic substrates. Using metal-phthalocyanines (MePc), a commonly used metal-organic complex as a model system, each chapter explores different aspects of the interaction with silver surfaces: the local adsorption geometry, self-assembly, the modifications of the electronic and magnetic characteristics due to hybridization and charge transfer, and finally the manipulation of molecular charge and spin states by electron doping using alkali atoms moved with the STM tip. | ||
650 | 0 |
_aphysics. _9566227 |
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650 | 0 |
_aChemistry, Organic. _9299058 |
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650 | 0 |
_aOptical materials. _9303073 |
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650 | 1 | 4 |
_aPhysics. _9566228 |
650 | 2 | 4 |
_aSurface and Interface Science, Thin Films. _9410813 |
650 | 2 | 4 |
_aOptical and Electronic Materials. _9303078 |
650 | 2 | 4 |
_aOrganometallic Chemistry. _9309445 |
650 | 2 | 4 |
_aSpectroscopy and Microscopy. _9369045 |
650 | 2 | 4 |
_aAtomic, Molecular, Optical and Plasma Physics. _9410421 |
710 | 2 |
_aSpringerLink (Online service) _9143950 |
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773 | 0 | _tSpringer eBooks | |
830 | 0 |
_aSpringer Theses, Recognizing Outstanding Ph.D. Research, _9567110 |
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856 | 4 | 0 | _uhttp://dx.doi.org/10.1007/978-3-319-02660-2 |
912 | _aZDB-2-PHA | ||
999 | _c400337 |