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008 160915s2014 gw | s |||| 0|eng d
020 _a9783319026602
_9978-3-319-02660-2
024 7 _a10.1007/978-3-319-02660-2
_2doi
035 _ato000542329
040 _aSpringer
_cSpringer
_dRU-ToGU
050 4 _aQC176.8.S8
050 4 _aQC611.6.S9
050 4 _aQC176.84.S93
072 7 _aPHFC
_2bicssc
072 7 _aSCI077000
_2bisacsh
082 0 4 _a530.417
_223
100 1 _aKrull, Cornelius.
_eauthor.
_9448775
245 1 0 _aElectronic Structure of Metal Phthalocyanines on Ag(100)
_helectronic resource
_cby Cornelius Krull.
260 _aCham :
_bSpringer International Publishing :
_bImprint: Springer,
_c2014.
300 _aXVII, 146 p. 81 illus., 54 illus. in color.
_bonline resource.
336 _atext
_btxt
_2rdacontent
337 _acomputer
_bc
_2rdamedia
338 _aonline resource
_bcr
_2rdacarrier
490 1 _aSpringer Theses, Recognizing Outstanding Ph.D. Research,
_x2190-5053
505 0 _aAbstract -- Introduction -- Molecular electronics -- Experimental techniques -- Introduction to the Kondo effect -- Adsorption of Metal Phthalocyanines on Ag(100) -- Electronic and magnetic properties of MePc on Ag(100) -- Doping of MePc: Alkali and Fe atoms -- Conclusions and Outlook -- Appendix: CuPc on Au(111).
520 _aThe application of molecules in technological devices hinges on the proper understanding of their behavior on metallic electrodes or substrates. The intrinsic molecular electronic and magnetic properties are modified at a metallic interface, and greatly depend on the atomic configuration of the molecule-metal bond. This poses certain problems, such as the lack of reproducibility in the transport properties of molecular junctions, but also offers the possibility to induce new charge and spin configurations that are only present at the interface. The results presented in this thesis address this issue, providing a comprehensive overview of the influence of molecule-metal and molecule-molecule interactions on the electronic and magnetic properties of molecules adsorbed on metallic substrates. Using metal-phthalocyanines (MePc), a commonly used metal-organic complex as a model system, each chapter explores different aspects of the interaction with silver surfaces: the local adsorption geometry, self-assembly, the modifications of the electronic and magnetic characteristics due to hybridization and charge transfer, and finally the manipulation of molecular charge and spin states by electron doping using alkali atoms moved with the STM tip.
650 0 _aphysics.
_9566227
650 0 _aChemistry, Organic.
_9299058
650 0 _aOptical materials.
_9303073
650 1 4 _aPhysics.
_9566228
650 2 4 _aSurface and Interface Science, Thin Films.
_9410813
650 2 4 _aOptical and Electronic Materials.
_9303078
650 2 4 _aOrganometallic Chemistry.
_9309445
650 2 4 _aSpectroscopy and Microscopy.
_9369045
650 2 4 _aAtomic, Molecular, Optical and Plasma Physics.
_9410421
710 2 _aSpringerLink (Online service)
_9143950
773 0 _tSpringer eBooks
830 0 _aSpringer Theses, Recognizing Outstanding Ph.D. Research,
_9567110
856 4 0 _uhttp://dx.doi.org/10.1007/978-3-319-02660-2
912 _aZDB-2-PHA
999 _c400337