000 03551nam a22005655i 4500
001 vtls000485084
003 RU-ToGU
005 20210922070104.0
007 cr nn 008mamaa
008 140715s2013 gw | s |||| 0|eng d
020 _a9783642391156
_9978-3-642-39115-6
024 7 _a10.1007/978-3-642-39115-6
_2doi
035 _ato000485084
040 _aSpringer
_cSpringer
_dRU-ToGU
050 4 _aQD505
072 7 _aPNRD
_2bicssc
072 7 _aSCI013060
_2bisacsh
082 0 4 _a541.395
_223
100 1 _aWu, Peng.
_eauthor.
_9326535
245 1 0 _aMWW-Type Titanosilicate
_h[electronic resource] :
_bSynthesis, Structural Modification and Catalytic Applications to Green Oxidations /
_cby Peng Wu, Hao Xu, Le Xu, Yueming Liu, Mingyuan He.
260 _aBerlin, Heidelberg :
_bSpringer Berlin Heidelberg :
_bImprint: Springer,
_c2013.
300 _aVIII, 125 p. 79 illus., 25 illus. in color.
_bonline resource.
336 _atext
_btxt
_2rdacontent
337 _acomputer
_bc
_2rdamedia
338 _aonline resource
_bcr
_2rdacarrier
490 1 _aSpringerBriefs in Molecular Science,
_x2191-5407
505 0 _aIntroduction -- Synthesis of Ti-MWW zeolite -- Post-synthesis modification of Ti-MWW: a door to diversity -- Catalytic properties of Ti-MWW in selective oxidation reactions -- Conclusions and Prospects.
520 _aThis book provides a comprehensive review of a new generation of selective oxidation titanosilicate catalysts with the MWW topology (Ti-MWW) based on the research achievements of the past 12 years. It gives an overview of the synthesis, structure modification and catalytic properties of Ti-MWW. Ti-MWW can readily be prepared by means of direct hydrothermal synthesis with crystallization-supporting agents, using dual-structure-directing agents and a dry-gel conversion technique. It also can be post-synthesized through unique reversible structure transformation and liquid-phase isomorphous substitution. The structural conversion of Ti-MWW into the materials usable for processing large molecules is summarized. Taking advantage of the structure diversity of the lamellar precursor of Ti-MWW, it can be fully or partially delaminated, and undergo interlayer silylation to obtain a novel structure with larger porosity. In the selective oxidation (alkene epoxidation and ketone/aldehyde ammoximation) with hydrogen peroxide or organic peroxide as an oxidant, the unique catalytic properties of Ti-MWW are described in comparison to conventional titanosilicates such as TS-1 and Ti-Beta.
650 0 _achemistry.
_9161768
650 0 _aChemistry, Physical organic.
_9566250
650 0 _aChemical engineering.
_9303336
650 0 _aCatalysis.
_9308199
650 0 _aEnvironmental Chemistry.
_9310548
650 1 4 _aChemistry.
_9161768
650 2 4 _aCatalysis.
_9308199
650 2 4 _aEnvironmental Chemistry.
_9310548
650 2 4 _aIndustrial Chemistry/Chemical Engineering.
_9303339
650 2 4 _aPhysical Chemistry.
_9566251
700 1 _aXu, Hao.
_eauthor.
_9416230
700 1 _aXu, Le.
_eauthor.
_9416231
700 1 _aLiu, Yueming.
_eauthor.
_9416232
700 1 _aHe, Mingyuan.
_eauthor.
_9416233
710 2 _aSpringerLink (Online service)
_9143950
773 0 _tSpringer eBooks
830 0 _aSpringerBriefs in Molecular Science,
_9410471
856 4 0 _uhttp://dx.doi.org/10.1007/978-3-642-39115-6
912 _aZDB-2-CMS
999 _c357749