000 | 02674nab a2200361 c 4500 | ||
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001 | vtls000531900 | ||
003 | RU-ToGU | ||
005 | 20210906224536.0 | ||
007 | cr | | ||
008 | 170613|2015 ru s a eng dd | ||
024 | 7 |
_a10.1134/S0036024415060102 _2doi |
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035 | _ato000531900 | ||
040 |
_aRU-ToGU _brus _cRU-ToGU |
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245 | 1 | 0 |
_aInfluence of the content of Mn2+ on the phase composition of the precursor of MnOx-Al2O3 catalyst and the catalytic activity in the oxidation reaction of methane _cS. I. Galanov, O. I. Sidorova, E. N. Gryaznova, L. N. Shiyan |
504 | _aБиблиогр.: 22 назв. | ||
520 | 3 | _aThe influence of the concentration of Mn2+ in a solution for the hydrolysis of nanosized aluminum powder on the phase composition of the precursor and the content of manganese in samples of aluminum hydroxide is studied. Stages of the formation of catalysts from the precursors are studied by means of synchronic thermogravimetric (TG)-differential scanning calorimetry (DSC) analysis and X-ray phase analysis (XPA). The influence of the number of manganese ions in aluminum hydroxide on the phase composition and catalytic properties of MnO x -Al2O3 systems in the reaction of the deep oxidation of methane is also studied. It is shown that an increase in the concentration of manganese ions in the solution for hydrolysis raises the content of unreacted aluminum and X-ray amorphous hydroxides in the precursors of the catalysts. It is established that the phase composition of the catalyst and the catalytic activity in the reaction of the deep oxidation of methane depend on the content of manganese in the precursor. | |
653 | _aкатализаторы | ||
653 | _aоксид марганца | ||
653 | _aоксид алюминия | ||
653 | _aокислительные реакции | ||
653 | _aметан | ||
655 | 4 |
_aстатьи в журналах _9681159 |
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700 | 1 |
_aGalanov, Sergey I. _9102431 |
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700 | 1 |
_aGryaznova, Elena N. _9102429 |
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700 | 1 |
_aShiyan, Ludmila N. _9102430 |
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700 | 1 |
_aSidorova, Olga I. _999977 |
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710 | 2 |
_aТомский государственный университет _bХимический факультет _bКафедра физической и коллоидной химии _983087 |
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773 | 0 |
_tRussian journal of physical chemistry A _d2015 _gVol. 89, № 6. P. 974-981 _x0036-0244 |
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852 | 4 | _aRU-ToGU | |
856 | 7 | _uhttp://vital.lib.tsu.ru/vital/access/manager/Repository/vtls:000531900 | |
908 | _aстатья | ||
999 | _c118597 |