Scientific Library of Tomsk State University

   E-catalog        

Image from Google Jackets
Normal view MARC view

Ethylene glycol oxidation over Ag-containing catalysts: A theoretical study M. Salaev, O. K. Poleshchuk, O. V. Vodyankina

By: Salaev, Mikhail AContributor(s): Poleshchuk, Oleg Kh | Vodyankina, Olga V | Томский государственный университет Химический факультет Кафедра физической и коллоидной химииMaterial type: ArticleArticleSubject(s): этиленгликоль | окисление | сереброGenre/Form: статьи в журналах Online resources: Click here to access online In: Journal of molecular catalysis A : chemical Vol. 396. P. 61-67Abstract: A theoretical interpretation of the mechanism of ethylene glycol oxidation to glyoxal over Ag-containing catalysts is considered. A model system, reflecting the interaction of Ag cluster with process adsorbates and/or intermediates, is proposed. Both partial oxidation of ethylene glycol to glyoxal and CO2 formation routes are reconstructed, and the corresponding reaction profiles are represented. The roles played by the most important reaction intermediates participating in the process under consideration are discussed.
Tags from this library: No tags from this library for this title. Log in to add tags.
No physical items for this record

A theoretical interpretation of the mechanism of ethylene glycol oxidation to glyoxal over Ag-containing catalysts is considered. A model system, reflecting the interaction of Ag cluster with process adsorbates and/or intermediates, is proposed. Both partial oxidation of ethylene glycol to glyoxal and CO2 formation routes are reconstructed, and the corresponding reaction profiles are represented. The roles played by the most important reaction intermediates participating in the process under consideration are discussed.

There are no comments on this title.

to post a comment.