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Синтез и исследование продуктов взаимодействия тетраметилолгликолурила и эпихлоргидрина К. В. Рубцов, А. А. Сорванов

By: Рубцов, Константин ВалерьевичContributor(s): Сорванов, Александр АлександровичMaterial type: ArticleArticleOther title: Synthesis and analysis of interaction products between tetramethylolglycoluril and epichlorohydrin [Parallel title]Subject(s): супрамолекулы | органические соединения | катализ | полимерные продукты | экспериментальные данные | триметиламин | эпихлоргидрин | ИК-спектроскопияGenre/Form: статьи в сборниках Online resources: Click here to access online In: Перспективы развития фундаментальных наук. Т. 2 : сборник научных трудов XV Международной конференции студентов, аспирантов и молодых ученых, 24–27 апреля 2018 г Т. 2 : Химия. С. 282-284Abstract: A new polymer was synthesized by interaction between epichlorohydrin and tetramethylolglycoluril in the presence of trimethylamine. The process was carried out in excess of epichlorohydrin and white insoluble substance was precipitated. It was shown that repeating unit of polymer contains fragments of epichlorohydrin and tetramethylolglycoluril. This polymer was found to be soluble in water and DMSO but insoluble in other organic solvents.
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A new polymer was synthesized by interaction between epichlorohydrin and tetramethylolglycoluril in the presence of trimethylamine. The process was carried out in excess of epichlorohydrin and white insoluble substance was precipitated. It was shown that repeating unit of polymer contains fragments of epichlorohydrin and tetramethylolglycoluril. This polymer was found to be soluble in water and DMSO but insoluble in other organic solvents.

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