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Polyoxomolybdates as Green Catalysts for Aerobic Oxidation electronic resource by Anjali Patel, Soyeb Pathan.

By: Patel, Anjali [author.]Contributor(s): Pathan, Soyeb [author.] | SpringerLink (Online service)Material type: TextTextSeries: SpringerBriefs in Molecular SciencePublication details: Cham : Springer International Publishing : Imprint: Springer, 2015Description: XI, 55 p. 35 illus., 23 illus. in color. online resourceContent type: text Media type: computer Carrier type: online resourceISBN: 9783319129884Subject(s): chemistry | Catalysis | Sustainable development | Materials Science | Chemistry | Catalysis | Sustainable Development | Characterization and Evaluation of MaterialsDDC classification: 541.395 LOC classification: QD505Online resources: Click here to access online
Contents:
Introduction -- Oxidation of alcohols catalyzed by Undecamolybdophosphate -- Oxidation of alcohols catalyzed by Transition Metal (Mn, Co, Ni, Cu)- Substituted Phosphomolybdates -- Conclusive remarks.
In: Springer eBooksSummary: Heterogeneously catalyzed selective oxidations of alcohols is a highly topical field. The first chapter of this brief describes the importance of the selective oxidation of alcohols and advantages of heterogeneous catalysts over conventional catalysts, use of environmentally benign oxidants, and the design of selective catalysts by tailoring of polyoxometalates at the molecular level. Chapter 2 describes synthesis, characterization 11-molybdophosphate based supported materials and their use as heterogeneous catalysts for oxidation of alcohols with molecular oxygen under solvent free mild reaction condition. ZrO2, Al2O3, MCM-41 and zeolite Hβ were used as supports. Chapter 3 describes synthesis, characterization of transition metals (Mn, Co, Ni, Cu)- substituted phosphomolybdates and their use as heterogeneous catalysts for oxidation of alcohols with molecular oxygen under solvent free mild reaction condition. Chapter 4 describes conclusive remarks for present catalytic systems.
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Introduction -- Oxidation of alcohols catalyzed by Undecamolybdophosphate -- Oxidation of alcohols catalyzed by Transition Metal (Mn, Co, Ni, Cu)- Substituted Phosphomolybdates -- Conclusive remarks.

Heterogeneously catalyzed selective oxidations of alcohols is a highly topical field. The first chapter of this brief describes the importance of the selective oxidation of alcohols and advantages of heterogeneous catalysts over conventional catalysts, use of environmentally benign oxidants, and the design of selective catalysts by tailoring of polyoxometalates at the molecular level. Chapter 2 describes synthesis, characterization 11-molybdophosphate based supported materials and their use as heterogeneous catalysts for oxidation of alcohols with molecular oxygen under solvent free mild reaction condition. ZrO2, Al2O3, MCM-41 and zeolite Hβ were used as supports. Chapter 3 describes synthesis, characterization of transition metals (Mn, Co, Ni, Cu)- substituted phosphomolybdates and their use as heterogeneous catalysts for oxidation of alcohols with molecular oxygen under solvent free mild reaction condition. Chapter 4 describes conclusive remarks for present catalytic systems.

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